Thermodynamics

Ideal gas laws, kinetic theory, heat transfer, thermodynamic processes, engines, and entropy.

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Ideal Gas & Kinetic Theory

  • PV = nRT = NkT.
  • Average KE per molecule (3D) = (3/2)kT; rms speed = √(3RT/M).
  • Pressure arises from molecular collisions with walls.

PV = nRT

⟨KE⟩ = ³⁄₂ kT

v_rms = √(3RT/M)

Laws & Processes

  • First law: ΔU = Q − W (sign convention dependent).
  • Isothermal: ΔU = 0; adiabatic: Q = 0; isobaric: constant P; isochoric: constant V.
  • Heat capacities: C_p − C_v = R (ideal gas).

ΔU = Q − W

C_p − C_v = R

TV^{γ−1} = const (adiabatic)

Engines & Entropy

  • Carnot efficiency: η = 1 − T_C/T_H (maximum possible between two reservoirs).
  • Entropy: dS = dQ_rev/T; entropy of universe increases for irreversible processes.
  • Second law: heat does not spontaneously flow from cold to hot.

η_Carnot = 1 − T_C/T_H

dS = đQ_rev/T

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