Thermodynamics
Ideal gas laws, kinetic theory, heat transfer, thermodynamic processes, engines, and entropy.
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Temperature and Kinetic Theory
Khan Academy

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Ideal Gas Law
Professor Dave Explains

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First Law of Thermodynamics
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PV Diagrams and Processes
Michel van Biezen

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Carnot Engine
Khan Academy

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Entropy
Professor Dave Explains
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Notes
Ideal Gas & Kinetic Theory
- PV = nRT = NkT.
- Average KE per molecule (3D) = (3/2)kT; rms speed = √(3RT/M).
- Pressure arises from molecular collisions with walls.
PV = nRT
⟨KE⟩ = ³⁄₂ kT
v_rms = √(3RT/M)
Laws & Processes
- First law: ΔU = Q − W (sign convention dependent).
- Isothermal: ΔU = 0; adiabatic: Q = 0; isobaric: constant P; isochoric: constant V.
- Heat capacities: C_p − C_v = R (ideal gas).
ΔU = Q − W
C_p − C_v = R
TV^{γ−1} = const (adiabatic)
Engines & Entropy
- Carnot efficiency: η = 1 − T_C/T_H (maximum possible between two reservoirs).
- Entropy: dS = dQ_rev/T; entropy of universe increases for irreversible processes.
- Second law: heat does not spontaneously flow from cold to hot.
η_Carnot = 1 − T_C/T_H
dS = đQ_rev/T
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